Relaxor ferroelectric-like behavior in 10PbTiO3–10Fe2O3–30V2O5–50B2O3 glass for energy storage applications

تاريخ النشر

11/08/2021 12:00:00 ص

79

المؤلفون

MM Ei-Desoky, NK Wally, AM Ali, Amany E Harby, Ahmed E Hannora

الوصف

Recently, demand increased for dielectric materials used in energy storage devices at high voltage applications. Appearance of polar clusters in glass matrix could promote its use in energy storage applications. Conventional quenched glass sample of composition 10PbTiO3–10Fe2O3–30V2O5–50B2O3 were successfully developed. The glassy nature was confirmed by XRD and DSC measurements. Boson peak observed at low frequency from the Raman spectra confirms polar cluster formation. Dielectric properties of prepared glass were investigated in a wide range of frequency and temperature. Broad and diffuse peak of dielectric permittivity shifted to the higher temperatures, denoting the typical relaxor ferroelectrics like behavior. Sample shows energy storage density of about 164.7 mJ/cm3 at room temperature. Quenched glass sample shows typical anti-ferromagnetic behavior.

URL

https://link.springer.com/article/10.1007/s10854-021-06727-3

DOI

10.1007/s10854-021-06727-3

الملخص

الكلمات الدالة